- Sep 11 Sun 2022 18:30
ScienceAAAS - 「架構師成長計劃」第二季|網絡智能化技術與演進
- Sep 11 Sun 2022 18:30
RSC英國皇家化學會 - 南大鄭麗敏團隊:利用 ZrH-Pr 光熱效應克服「光響應質子傳導」挑戰
- Sep 11 Sun 2022 18:30
RSC英國皇家化學會 - 科學創造營 | 名師講堂金秋再啟: SDG6 清潔用水和公共衛生專場
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暑威盡退,秋意漸濃。在史上最熱夏季剛剛退散腳步,涼爽秋風即將吹起之際,RSC 科學創造營「名師講堂」系列線上研討會於 9 月再次開啟!
- Sep 11 Sun 2022 18:30
Paper繪圖 - Endnote: 如何下載並引用參考文獻?
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- Sep 11 Sun 2022 18:30
Paper繪圖 - 果斷收藏 | 三個R語言繪圖網站
大家都知道,平時使用R語言繪圖的時候,最麻煩的一點就是需要記代碼,雖然說RStudio有代碼提示功能,但有的時候,還是記不住。因此收藏一些常見的R語言繪圖的網站,能快速找到繪圖的代碼進行科研繪圖是尤為必要的。
下來我們就說說三個網站吧:
- Sep 11 Sun 2022 18:30
MOFs在線 - Recent development of photo- and electroactive HOFs
HOFs are a class of crystalline porous materials with predictable topologies and tunable structures. Initially hindered by relatively weak hydrogen-bonding interactions, as many HOFs collapse upon guest solvent removal. Recently, designing constructors with large π-conjugated systems to form intermolecular shape-fitting π-π stacking interactions can greatly enhance the thermal stability of HOFs. More importantly, these HOFs with large π-conjugated structures can accelerate electron transfer when redox reactions occur due to the overlapping steric orbital interactions. These intrinsic optoelectronic properties make HOFs an attractive and unique class of photoactive and electroactive porous materials for catalysis, sensing, and biomedical applications. Based on the shape-fitting π-π stacking strategy, various photoactive and electroactive HOFs with excellent properties have been constructed by using various ligands containing photosensitive or redox-active organic cores with hydrogen-bonding sites. This brief review summarizes recent advances in the development of optically and electroactive HOFs, including synthetic methods and various applications.
However, the development and application of HOFs are still in their infancy compared to mature MOFs and COFs, so there are still many challenges to overcome and potential opportunities to embrace HOFs. First, the potential of HOFs in the field of electrocatalysis remains to be exploited. Second, although HOFs show great potential in heterogeneous catalysis, their nanoscale to microscale morphologies have not been systematically investigated. The morphology of MOF-based catalysts has been shown to be a key influencing factor in determining the catalytic performance. Due to the solution processability and adaptability of HOF, there are many opportunities to explore the effect of HOF morphology on performance. Third, the introduction of metal nanoparticles into the nanopores of HOFs significantly broadens and enhances the possible applications of HOFs. However, the possible coordination interactions between metal ions and hydrogen-bonding sites can lead to the formation of metal-ligand complexes and affect the phase purity of HOFs. Therefore, care should be taken to avoid this situation. In conclusion, although HOFs have shown great promise as functional photoactive and electroactive materials so far, this exciting research area still needs a lot of research work to realize its full potential.
- Sep 11 Sun 2022 18:30
MOFs在線 - Building MOFs scaffolds using exotic elements
Building scaffolds using exotic elements: Research team succeeds in creating novel metal-organic frameworks
- Sep 11 Sun 2022 18:30
MOFs在線 - Anal. Chem.:混合調控自增強發光Eu-MOF作為定向抗體裝飾生物傳感平台的ECL信號探針
- Sep 11 Sun 2022 18:30
MaterialsViews - 【AM】酷!液體作畫
- Sep 11 Sun 2022 18:30
MaterialsViews - 【SmartMat】6期專刊,豐富您的假期閱讀